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581-590 von 601 Publikationen
Zeitschriftenartikel
First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands
(2018)
Zeitschriftenartikel
Hydrosilane Synthesis by Catalytic Hydrogenolysis of Chlorosilanes and Silyl Triflates
(2018)
Zeitschriftenartikel
Iron‐Electrocatalyzed C−H Arylations: Mechanistic Insights into Oxidation‐Induced Reductive Elimination for Ferraelectrocatalysis
(2019)
Despite major advances, organometallic C-H transformations are dominated by precious 5d and 4d transition metals, such as iridium, palladium and rhodium. In contrast, the unique potential of less toxic Earth-abundant 3d ...
Zeitschriftenartikel
Sequential Double Dearomatization of the Pyrazolate-Based “Two-in-One” Pincer Ligand in a Dinuclear Rhodium(I) Complex
(2019)
A binucleating pyrazolate‐based ligand providing two tridentate PNN compartments is shown to form a dinuclear rhodium(I) complex [L{Rh(CO)}2](PF6) (1) that can be deprotonated at both side arm methylene groups between ...
Zeitschriftenartikel
An Unprecedented Fully H - Substituted Phosphate Hydride Sr5(PO4)3H Expanding the Apatite Family
(2019)
The apatite family is a mineral class that also contains the biologically very important hydroxyapatite. Here, we are reporting on the synthesis and characterization of a fully hydride‐substituted strontium apatite, which ...
Zeitschriftenartikel
Electrochemical Access to Aza-Polycyclic Aromatic Hydrocarbons: Rhoda-Electrocatalyzed Domino Alkyne Annulations
(2020)
Nitrogen-doped polycyclic aromatic hydrocarbons (aza-PAHs) have found broad applications in material sciences. Herein, a modular electrochemical synthesis of aza-PAHs was developed via a rhodium-catalyzed cascade C-H ...