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Rational Design of Chiral Selenium-π-Acid Catalysts
(2019)
A series of unprecedented chiral selenium- -acid catalysts for the asymmetric, oxidative
functionalization of alkenes has been developed. In total, eleven different chiral dihydrodiselenocine
and (di-)alkoxyphenyl ...
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Air-Stable Secondary Phosphine Oxides for Nickel-Catalyzed Cross-Couplings of Aryl Ethers by C–O Activation
(2019)
Air- and moisture-stable secondary phosphine oxides (SPOs) enabled nickel-catalyzed Kumada–Corriu cross-couplings of various arylmethyl ethers at room temperature by challenging C–O activation.
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Di- and Tetrairon(III) μ-Oxido Complexes of an N3S-Donor Ligand: Catalyst Precursors for Alkene Oxidations
(2019)
The new di- and tetranuclear Fe(III) μ-oxido complexes [Fe4(μ-O)4(PTEBIA)4](CF3SO3)4(CH3CN)2] (1a), [Fe2(μ-O)Cl2(PTEBIA)2](CF3SO3)2 (1b), and [Fe2(μ-O)(HCOO)2(PTEBIA)2](ClO4)2 (MeOH) (2) were prepared from the sulfur-containing ...
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High-resolution experimental and computational electrophysiology reveals weak β-lactam binding events in the porin PorB
(2019)
The permeation of most antibiotics through the outer membrane of Gram-negative bacteria occurs through porin channels. To design drugs with increased activity against Gram-negative bacteria in the face of the antibiotic ...
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Four- and Five-Coordinate Osmium(IV) Nitrides and Imides: Circumventing the “Nitrido Wall”
(2017)
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Photochemically Driven Reverse Water-Gas Shift at Ambient Conditions mediated by a Nickel Pincer Complex
(2018)
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Accurate Probabilities for Highly Activated Reaction of Polyatomic Molecules on Surfaces Using a High-Dimensional Neural Network Potential: CHD 3 + Cu(111)
(2019)
An accurate description of reactive scattering of molecules on metal surfaces often requires the modeling of energy transfer between the molecule and the surface phonons. Although ab initio molecular dynamics (AIMD) can ...
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Inhibition of proteasome rescues a pathogenic variant of respiratory chain assembly factor COA7
(2019)
Nuclear and mitochondrial genome mutations lead to various mitochondrial diseases, many of which affect the mitochondrial respiratory chain. The proteome of the intermembrane space (IMS) of mitochondria consists of several ...
Zeitschriftenartikel
Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer
(2019)
The isolable complex [Os(PHMes*)H(PNP)] (Mes*=2,4,6-t Bu3 C6 H3 ; PNP=N{CHCHPt Bu2 }2 ) exhibits high phosphinyl radical character. This compound offers access to the phosphinidene complex [Os(PMes*)H(PNP)] by P-H proton ...