The reaction of HN[P(NMe2)2NSiMe3]2 with NaH and KH in 1 : 1 molar ratio yielded a dimer {NaN[P(NMe2)2NSiMe3]2}21 and a polymer {KN[P(NMe2)2NSiMe3]22 with a zigzag chain structure, respectively. The reaction of Ca[N(SiMe3)2]2·2thf ...

Zentrale NaF- und MgF2,-Gerüste enthalten die bei der Reaktion von [Cp*TiF3](Cp* = C5Me5) mit elementarem Natrium bzw. Magnesium gebildeten Titelverbindungen. Bei diesen Umsetzungen wird TiIV zu TiIII reduziert. Die ...

Central NaF and MgF2 frameworks are present in the title compounds obtained from the reaction of [Cp*TiF3] (Cp C5Me5) with elemental sodium and magnesium, respectively. In these reactions TiIV is reduced to TiIII. The ...

Reaction of LiN(SiMe3)2 with Cp2p. and pmdeta produces (Cp)(Me3Si)2NSn(µ,-Cp)Li·pmdeta 1 which can be viewed as a model intermediate for nucleophilic substitution of Cp2Sn.

[(thf)3Na{(pz)3Ge}]1 and [(thf)2(pzH)Na{(pz)3Sn}]22(pz = pyrazol-1-yl) are obtained by the reaction of pzNa with GeCl2·dioxane and SnCl2, respectively, in a 3 : 1 molar ratio in thf (thf = tetrahydrofuran); the X-ray ...

Alkali- and alkaline-earth-metal iminoaminosulfinates have been synthesised and characterized by X-ray diffraction and solid-state NMR investigations. The viability of metal-exchange reactions has been demonstrated resulting ...

Reaction of the square-pyramidal cluster [Ru5C(CO)15]1 with cyclohexa-1,3-diene and Me3NO in CH2Cl2 at ambient temperature affords the novel species [Ru5C(CO)13(µ-2:2-C6H8)]2 which has been fully characterized by X-ray ...