| dc.contributor.author | Jana, Anukul | |
| dc.contributor.author | Leusser, Dirk | |
| dc.contributor.author | Objartel, Ina | |
| dc.contributor.author | Roesky, Herbert W. | |
| dc.contributor.author | Stalke, Dietmar | |
| dc.date.accessioned | 2013-03-14T12:41:24Z | |
| dc.date.available | 2013-03-14T12:41:24Z | |
| dc.date.issued | 2011 | |
| dc.identifier.citation | Jana, Anukul; Leusser, Dirk; Objartel, Ina; Roesky, Herbert W.; Stalke, Dietmar (2011): A stable silicon(ii) monohydride | |
| dc.relation.ISSN | 1477-9234 | |
| dc.identifier.uri | http://resolver.sub.uni-goettingen.de/purl?gs-1/8690 | |
| dc.description.abstract | A stable silicon(II) monohydride is accomplished through a covalent shared interaction of the silylene
lone-pair and a sp3-hybridized boron atom of the Lewis acidic BH3. Experimental charge density
investigations reveal a central positively charged silicon atom bound to a negatively charged hydrogen
atom. The positively charged H–Si–BH3 moiety is coordinated by the lone-pairs of electrons of the
benzamidinate ligand. This coordination is reinforced by a transannular Si1 ... C1 privileged exchange
channel. | |
| dc.language.iso | eng | |
| dc.rights | openAccess | |
| dc.subject | silicon(II) dihydride; silicon chemistry | |
| dc.title | A stable silicon(ii) monohydride | |
| dc.type | journalArticle | |
| dc.identifier.doi | 10.1039/c0dt01675f | |
| dc.type.version | publishedVersion | |
| dc.identifier.fs | 584131 | |
| dc.bibliographicCitation.volume | 40 | |
| dc.bibliographicCitation.issue | 20 | |
| dc.bibliographicCitation.firstPage | 5458 | |
| dc.bibliographicCitation.lastPage | 5463 | |
| dc.type.subtype | journalArticle | |
| dc.notes | This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively. | |
| dc.description.status | peerReviewed | |
| dc.bibliographicCitation.journal | Dalton Transactions | |
