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A stable silicon(ii) monohydride

dc.contributor.authorJana, Anukul
dc.contributor.authorLeusser, Dirk
dc.contributor.authorObjartel, Ina
dc.contributor.authorRoesky, Herbert W.
dc.contributor.authorStalke, Dietmar
dc.date.accessioned2013-03-14T12:41:24Z
dc.date.available2013-03-14T12:41:24Z
dc.date.issued2011
dc.identifier.citationJana, Anukul; Leusser, Dirk; Objartel, Ina; Roesky, Herbert W.; Stalke, Dietmar (2011): A stable silicon(ii) monohydride
dc.relation.ISSN1477-9234
dc.identifier.urihttp://resolver.sub.uni-goettingen.de/purl?gs-1/8690
dc.description.abstractA stable silicon(II) monohydride is accomplished through a covalent shared interaction of the silylene lone-pair and a sp3-hybridized boron atom of the Lewis acidic BH3. Experimental charge density investigations reveal a central positively charged silicon atom bound to a negatively charged hydrogen atom. The positively charged H–Si–BH3 moiety is coordinated by the lone-pairs of electrons of the benzamidinate ligand. This coordination is reinforced by a transannular Si1 ... C1 privileged exchange channel.
dc.language.isoeng
dc.rightsopenAccess
dc.subjectsilicon(II) dihydride; silicon chemistry
dc.titleA stable silicon(ii) monohydride
dc.typejournalArticle
dc.identifier.doi10.1039/c0dt01675f
dc.type.versionpublishedVersion
dc.identifier.fs584131
dc.bibliographicCitation.volume40
dc.bibliographicCitation.issue20
dc.bibliographicCitation.firstPage5458
dc.bibliographicCitation.lastPage5463
dc.type.subtypejournalArticle
dc.notesThis publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
dc.description.statuspeerReviewed
dc.bibliographicCitation.journalDalton Transactions


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