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Solution structures of alkali metal cyclopentadienides in THF estimated by ECC-DOSY NMR-spectroscopy (incl. software).

dc.contributor.authorBachmann, Sebastian
dc.contributor.authorGernert, Björn
dc.contributor.authorStalke, Dietmar
dc.date.accessioned2016-10-13T07:36:55Z
dc.date.available2016-10-13T07:36:55Z
dc.date.issued2016-10-12
dc.identifier.citationBachmann, Sebastian; Gernert, Björn; Stalke, Dietmar (2016): Solution structures of alkali metal cyclopentadienides in THF estimated by ECC-DOSY NMR-spectroscopy (incl. software). - Chemical communications (Cambridge, England), p.
dc.relation.ISSN1364-548X
dc.identifier.urihttp://resolver.sub.uni-goettingen.de/purl?gs-1/13768
dc.description.abstractIn this paper we present the aggregational motifs of the widely used alkali-metal cyclopentadienides (CpLi, CpNa, CpK, CpRb, CpCs) in THF-d8 solution estimated by ECC-DOSY NMR spectroscopy. They form monomeric contact ion pairs (CIPs) in THF-d8 solution, whereas in NH3 solvent-separated ion pairs (SSIPs) are observed. The applicability of ECC-DOSY is further advanced by introducing ECC-MW estimation software.
dc.format.extent4
dc.language.isoeng
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/
dc.subjectSolution structures; alkali metal cyclopentadienides; THF; ECC-DOSY NMR-spectroscopy
dc.titleSolution structures of alkali metal cyclopentadienides in THF estimated by ECC-DOSY NMR-spectroscopy (incl. software).
dc.typejournalArticle
dc.identifier.doi10.1039/c6cc07273a
dc.type.versionpublishedVersion
dc.type.subtypejournalArticle
dc.identifier.pmid27731871
dc.description.statuspeerReviewed
dc.bibliographicCitation.journalChemical communications (Cambridge, England)


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