dc.contributor.author | Scheibel, Markus G. | |
dc.contributor.author | Abbenseth, Josh | |
dc.contributor.author | Kinauer, Markus | |
dc.contributor.author | Heinemann, Frank W. | |
dc.contributor.author | Würtele, Christian | |
dc.contributor.author | de Bruin, Bas | |
dc.contributor.author | Schneider, Sven | |
dc.date.accessioned | 2015-11-03T11:30:10Z | |
dc.date.available | 2015-11-03T11:30:10Z | |
dc.date.issued | 2015-10-05 | |
dc.identifier.citation | Scheibel, Markus G; Abbenseth, Josh; Kinauer, Markus; Heinemann, Frank W; Würtele, Christian; de Bruin, Bas; Schneider, Sven (2015): Homolytic N-H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species. - Inorganic chemistry, Vol. 54, Nr. 19, p. 9290-302 | |
dc.relation.ISSN | 1520-510X | |
dc.identifier.uri | http://resolver.sub.uni-goettingen.de/purl?gs-1/12282 | |
dc.description.abstract | The redox series [Ir(n)(NHx)(PNP)] (n = II-IV, x = 3-0; PNP = N(CHCHPtBu2)2) was examined with respect to electron, proton, and hydrogen atom transfer steps. The experimental and computational results suggest that the Ir(III) imido species [Ir(NH)(PNP)] is not stable but undergoes disproportionation to the respective Ir(II) amido and Ir(IV) nitrido species. N-H bond strengths are estimated upon reaction with hydrogen atom transfer reagents to rationalize this observation and are used to discuss the reactivity of these compounds toward E-H bond activation. | |
dc.language | eng | |
dc.language.iso | eng | |
dc.relation | info:eu-repo/grantAgreement/EC/FP7/202886/EU/Catalytic Carbene Insertion Reactions; Creating Diversity in (Material) Synthesis/CATCIR | |
dc.rights | openAccess | |
dc.subject | Ammonia; Homolytic N−H Activation; Iridium Ammine; | |
dc.title | Homolytic N-H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species. | |
dc.type | journalArticle | |
dc.identifier.doi | 10.1021/acs.inorgchem.5b00829 | |
dc.type.version | publishedVersion | |
dc.bibliographicCitation.volume | 54 | |
dc.bibliographicCitation.issue | 19 | |
dc.bibliographicCitation.firstPage | 9290 | |
dc.bibliographicCitation.lastPage | 9302 | |
dc.type.subtype | journalArticle | |
dc.identifier.pmid | 26192601 | |
dc.relation.euproject | CATCIR | |
dc.description.status | peerReviewed | |
dc.bibliographicCitation.journal | Inorganic chemistry | |