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Homolytic N-H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species.

dc.contributor.authorScheibel, Markus G.
dc.contributor.authorAbbenseth, Josh
dc.contributor.authorKinauer, Markus
dc.contributor.authorHeinemann, Frank W.
dc.contributor.authorWürtele, Christian
dc.contributor.authorde Bruin, Bas
dc.contributor.authorSchneider, Sven
dc.date.accessioned2015-11-03T11:30:10Z
dc.date.available2015-11-03T11:30:10Z
dc.date.issued2015-10-05
dc.identifier.citationScheibel, Markus G; Abbenseth, Josh; Kinauer, Markus; Heinemann, Frank W; Würtele, Christian; de Bruin, Bas; Schneider, Sven (2015): Homolytic N-H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species. - Inorganic chemistry, Vol. 54, Nr. 19, p. 9290-302
dc.relation.ISSN1520-510X
dc.identifier.urihttp://resolver.sub.uni-goettingen.de/purl?gs-1/12282
dc.description.abstractThe redox series [Ir(n)(NHx)(PNP)] (n = II-IV, x = 3-0; PNP = N(CHCHPtBu2)2) was examined with respect to electron, proton, and hydrogen atom transfer steps. The experimental and computational results suggest that the Ir(III) imido species [Ir(NH)(PNP)] is not stable but undergoes disproportionation to the respective Ir(II) amido and Ir(IV) nitrido species. N-H bond strengths are estimated upon reaction with hydrogen atom transfer reagents to rationalize this observation and are used to discuss the reactivity of these compounds toward E-H bond activation.
dc.languageeng
dc.language.isoeng
dc.relationinfo:eu-repo/grantAgreement/EC/FP7/202886/EU/Catalytic Carbene Insertion Reactions; Creating Diversity in (Material) Synthesis/CATCIR
dc.rightsopenAccess
dc.subjectAmmonia; Homolytic N−H Activation; Iridium Ammine;
dc.titleHomolytic N-H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species.
dc.typejournalArticle
dc.identifier.doi10.1021/acs.inorgchem.5b00829
dc.type.versionpublishedVersion
dc.bibliographicCitation.volume54
dc.bibliographicCitation.issue19
dc.bibliographicCitation.firstPage9290
dc.bibliographicCitation.lastPage9302
dc.type.subtypejournalArticle
dc.identifier.pmid26192601
dc.relation.euprojectCATCIR
dc.description.statuspeerReviewed
dc.bibliographicCitation.journalInorganic chemistry


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